The best first team striker I’ve seen finishing one to one’s was Lineker. The only other one since then who came close was Lukaku. It’s a hard skill to master.
Deffo mate, look at Calvert Lewin as an examples. Decent at lots of different things but one on one you'd probably get decent odds of him actually slotting.
Some players just seem to have a natural ability to slot and don't complicate things when through on goal.